Area of research
Materials Chemistry · Electronic, Optical and Magnetic Materials
Research interest
Research topics from publications: Pressure‐Driven Orbital Reorientations and Coordination‐Sphere Reconstructions in [CuF2(H2O)2(pyz)]. Representative work: Successive reorientations of the Jahn–Teller axes associated with the CuII ions accompany a series of pronounced structural transitions in the title compound, as is shown by X-ray crystallography and high-frequency EPR measurements. The second transition forces a dimerization involving two thirds of the CuII sites due to ejection of one of the water molecules from the coordination sphere Wiederholte Umorientierungen der Jahn-Teller-Achsen durch die CuII-Ionen begleiten eine Reihe von ausgeprägten Strukturänderungen in der Titelverbindung, wie Röntgenstrukturanalyse und Hochfrequenz-EPR-Messungen ergaben. Die zweite Änderung erzwingt eine Dimerisierung von zwei der drei CuII-Positionen als Folge des Ausstoßes von einem der Wassermoleküle aus der Koordinationssphäre. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting infor