Area of research
Materials Chemistry · Organic Chemistry
Research interest
Research interests include Crystallization and Solubility Studies, X-ray Diffraction in Crystallography, Organoboron and organosilicon chemistry, and Synthesis and characterization of novel inorganic/organometallic compounds.
From Phosphinimines to Four‐Membered SiCPN Cations: Insights Into N–Si Bonding and Ring Strain
Where Does the Proton Go? Structure and Dynamics of Hydrogen‐Bond Switching in Aminophosphine Chalcogenides
Wohin geht das Proton? Struktur und Dynamik der Wasserstoffbrückenbindungsschaltung in Aminophosphinchalkogeniden
Si−H Activation via Dynamic Permutational Isomerism: A Ligand‐Directed Route to Dehydrogenative Coupling
Si─H‐Aktivierung durch dynamische Permutationsisomerie: Ein ligandengesteuerter Weg zur dehydrierenden Kupplung
CO <sub>2</sub> Unlocks Reactivity: Boryl Silyl Ketene Acetals Enable Mild and Direct C═C Bond Cleavage
Regio-, diastereo- and enantioselectivity in the photocatalytic generation of carbanions <i>via</i> hydrogen atom transfer and reductive radical-polar crossover
A Powerful P−N Connection: Preparative Approaches, Reactivity, and Applications of <i>P</i>‐Stereogenic Aminophosphines
A Cyclic Phosphonium Ion with an Asymmetrically Substituted Selenide‐Stabilized Silicon Center: Synthesis, Structure, and Substituent Effects
Stereochemically Pure <i>Si</i>‐Chiral Aminochlorosilanes
Low and High <i>Z′</i> Polymorphs of Dibenzyldiphenylsilane: A Hydrocarbon-Patterned Molecular Crystalline System
A molecular recognition motif for controlling 1:1 co-crystallization of two diastereomers
Structural and Electronic Effects on Phosphine Chalcogenide Stabilized Silicon Centers in Four-Membered Heterocyclic Cations
Hidden silylium-type reactivity of a siloxane-based phosphonium–hydroborate ion pair
Access to Enantiomerically Pure<i>P</i>‐Stereogenic Primary Aminophosphine Sulfides under Reductive Conditions
Influence of Amino Functions on the Coordination Ability of Silyl Ethers and Disiloxanes
Crystal Structure and Hirshfeld Surface Analysis of Trimethoxy(1‐naphthyl)silane – Intermolecular Interactions in a One‐Component Single‐Crystalline Trimethoxysilane
Chloropentaphenyldisiloxane—Model Study on Intermolecular Interactions in the Crystal Structure of a Monofunctionalized Disiloxane
Functional Group Variation in <i>tert</i>‐Butyldiphenylsilanes (TBDPS): Syntheses, Reactivities, and Effects on the Intermolecular Interaction Pattern in the Molecular Crystalline State
Molecular Scissors for Tailor‐Made Modification of Siloxane Scaffolds
Primary Amine Functionalization of Alkoxysilanes: Synthesis, Selectivity, and Mechanistic Insights
Interplay of Hydrogen and Halogen Bonding in the Crystal Structures of 2,6‐Dihalogenated Phenols
The crystal structure of adamantylmethoxydiphenylsilane, C<sub>23</sub>H<sub>28</sub>OSi
Easy Access to Enantiomerically Pure Heterocyclic Silicon‐Chiral Phosphonium Cations and the Matched/Mismatched Case of Dihydrogen Release
The crystal structure of the first ether solvate of hexaphenyldistannane [(Ph <sub>3</sub> Sn) <sub>2</sub> • 2 THF]
Controlled Synthesis and Molecular Structures of Methoxy‐, Amino‐, and Chloro‐Functionalized Disiloxane Building Blocks
Complexation behaviour of LiCl and LiPF<sub>6</sub>– model studies in the solid-state and in solution using a bidentate picolyl-based ligand
Unusual Coordination Pattern of the Lithium Center in a Chiral α-Lithiated Silicon Compound
The crystal structure of the triclinic polymorph of hexameric (trimethylsilyl)methyllithium, C<sub>24</sub>H<sub>66</sub>Li<sub>6</sub>Si<sub>6</sub>
Selective Si−C(sp<sup>3</sup>) Bond Cleavage in (Aminomethyl)silanes by Carbanionic Nucleophiles and Its Stereochemical Course