Debasish Mandal

Structure and reactivity/selectivity control by oriented-external electric fields

Kinetic Isotope Effect Determination Probes the Spin of the Transition State, Its Stereochemistry, and Its Ligand Sphere in Hydrogen Abstraction Reactions of Oxoiron(IV) Complexes

Catalysis of Methyl Transfer Reactions by Oriented External Electric Fields: Are Gold–Thiolate Linkers Innocent?

Simple Bisthiocarbonohydrazone as a Sensitive, Selective, Colorimetric, and Ratiometric Fluorescent Chemosensor for Picric Acids

Privileged Role of Thiolate as the Axial Ligand in Hydrogen Atom Transfer Reactions by Oxoiron(IV) Complexes in Shaping the Potential Energy Surface and Inducing Significant H-Atom Tunneling

A chromogenic and ratiometric fluorogenic probe for rapid detection of a nerve agent simulant DCP based on a hybrid hydroxynaphthalene–hemicyanine dye

Oxoiron(IV) Tetramethylcyclam Complexes with Axial Carboxylate Ligands: Effect of Tethering the Carboxylate on Reactivity

Structure and spin state of nonheme Fe^IVO complexes depending on temperature: predictive insights from DFT calculations and experiments

A benzopyrylium–phenothiazine conjugate of a flavylium derivative as a fluorescent chemosensor for cyanide in aqueous media and its bioimaging

“Turn-on” fluorescence sensing of cytosine: development of a chemosensor for quantification of cytosine in human cancer cells

A reactive primary fluorescence switch-on sensor for Hg2+ and the generated fluorophore as secondary recognition receptor toward Cu2+ in aqueous acetonitrile solution

Oriented electric fields as future smart reagents in chemistry

Interplay of Tunneling, Two-State Reactivity, and Bell–Evans–Polanyi Effects in C–H Activation by Nonheme Fe(IV)O Oxidants

Emergence of Function in P450-Proteins: A Combined Quantum Mechanical/Molecular Mechanical and Molecular Dynamics Study of the Reactive Species in the H₂O₂-Dependent Cytochrome P450_SPα and Its Regio- and Enantioselective Hydroxylation of Fatty Acids

A simple Schiff base molecular logic gate for detection of Zn2+ in water and its bio-imaging application in plant system

Benzthiazole-derived chromogenic, fluorogenic and ratiometric probes for detection of hydrazine in environmental samples and living cells

Reaction-based sensing of fluoride ions using desilylation method for triggering excited-state intramolecular proton transfer

Installation of efficient quenching groups of a fluorescent probe for the specific detection of cysteine and homocysteine over glutathione in solution and imaging of living cells

Interplay of Experiment and Theory in Elucidating Mechanisms of Oxidation Reactions by a Nonheme Ru^IVO Complex

A cyclization-induced emission enhancement (CIEE)-based ratiometric fluorogenic and chromogenic probe for the facile detection of a nerve agent simulant DCP

Determination of Spin Inversion Probability, H-Tunneling Correction, and Regioselectivity in the Two-State Reactivity of Nonheme Iron(IV)-Oxo Complexes

A BODIPY/pyrene-based chemodosimetric fluorescent chemosensor for selective sensing of hydrazine in the gas and aqueous solution state and its imaging in living cells

Colorimetric and ratiometric fluorescent chemodosimeter for selective sensing of fluoride and cyanide ions: tuning selectivity in proton transfer and C–Si bond cleavage

Oxoiron(IV) Complex of the Ethylene-Bridged Dialkylcyclam Ligand Me₂EBC

Colorimetric and ratiometric fluorescent chemosensor for fluoride ions based on phenanthroimidazole (PI): spectroscopic, NMR and density functional studies

How Does Tunneling Contribute to Counterintuitive H-Abstraction Reactivity of Nonheme Fe(IV)O Oxidants with Alkanes?

An azodye–rhodamine-based fluorescent and colorimetric probe specific for the detection of Pd²⁺ in aqueous ethanolic solution: synthesis, XRD characterization, computational studies and imaging in live cells

A pyrene thiazole conjugate as a ratiometric chemosensor with high selectivity and sensitivity for tin (Sn⁴⁺) and its application in imaging live cells