Area of research
Organic Chemistry · Nuclear and High Energy Physics
Research interest
Research interests include Catalytic C–H Functionalization Methods, Asymmetric Synthesis and Catalysis, Astrophysics and Cosmic Phenomena, and Sulfur-Based Synthesis Techniques.
Photocatalytic generation of alkoxysulfonium ions for selective oxidation of benzylic/allylic halides to carbonyls under base-free conditions.
A Visible Light-Responsive, Fast Room-Temperature Self- Healing, Mechanically Robust, Antibacterial Waterborne Polyurethane Based on Triple Dynamic Bonds
Photocatalytic Site-Selective Addition of Carbazole C(<i>sp</i><sup>2</sup>)-H Bonds to Aroylformates: Synthesis of α-Quaternary α-Hydroxyesters.
Visible-Light-Induced Intramolecular Dehydrogenative Cyclization of <i>o</i>-Aryl Benzaldehydes.
Metal- and oxidant-free carbonylation of benzylic and allylic C–H bonds with H<sub>2</sub>O <i>via</i> dual oxidative radical-polar crossover
Cross-Coupling of Benzylic and Aldehydic C-H Bonds via Photocatalytic Tandem Radical-Radical Coupling and Acceptorless Alcohol Dehydrogenation.
Phosphine-Mediated Reductive Insertion of α-Keto Esters and Isatins into Phthalic Anhydride Derivatives.
Metal-free acceptorless dehydrogenative cross-coupling of aldehydes/alcohols with alcohols
Photochemical Hydrogen Atom Transfer Catalysis for Dehydrogenation of Alcohols To Form Carbonyls.
Chemo- and Diastereoselective Synthesis of Spirooxindole-pyrazolines and Pyrazolones via P(NMe<sub>2</sub>)<sub>3</sub>-Mediated Substrate-Controlled Annulations of Azoalkenes with α-Dicarbonyl Compounds.
Phosphine-catalyzed divergent reactivity of alkynoates with acid anhydrides: chemo- and stereoselective synthesis of polysubstituted olefins and dienes
Unveiling Extreme Photoreduction Potentials of Donor–Acceptor Cyanoarenes to Access Aryl Radicals from Aryl Chlorides
Unveiling Extreme Photoreduction Potentials of Donor-Acceptor Cyanoarenes to Access Aryl Radicals from Aryl Chlorides.
Recent advances in visible-light photocatalytic deuteration reactions
Metal-free hydrogen evolution cross-coupling enabled by synergistic photoredox and polarity reversal catalysis
Application of the stabilization effect of a silyl group in radical-polar crossover reactions enabled by photoredox-neutral catalysis
Recent Advances in Phosphine‐Promoted (4 + 1) Annulation Reactions
Chemo- and Diastereoselective Synthesis of Pyrrolidines from Aroylformates and δ-Tosylamino Enones via P(NMe<sub>2</sub>)<sub>3</sub>-Mediated Reductive Amination/Base-Catalyzed Michael Addition Cascade.
Condensation of 1,2-dicarbonyl compounds with modified Huisgen zwitterions: synthesis of<i>N</i>-aryl–<i>N</i>-acyl hydrazones
Visible-light-mediated deuteration of silanes with deuterium oxide
Visible-light-mediated deuteration of silanes with deuterium oxide.
Visible‐Light‐Mediated Regioselective Allylation, Benzylation, and Silylation of Methylene‐Malononitriles via Photoredox‐Induced Radical Cation Fragmentation
<i>N</i>-Alkynylthio Phthalimide: A Shelf-Stable Alkynylthio Transfer Reagent for the Synthesis of Alkynyl Thioethers.
Phosphine-Catalyzed Chemo- and Diastereoselective [2 + 2 + 2] and [3 + 2] Annulations of γ-Methyl Allenoates with Doubly Activated Olefins: Syntheses of Highly Substituted Cyclohexanes and Cyclopentenes.
Phosphine‐Catalyzed [3+2] and [2+4] Annulations of γ‐Methyl Allenoates with Aryl α‐Keto Esters: Stereoselective Syntheses of Functionalized Tetrahydrofurans and 4‐Chromanols
Visible‐Light‐Mediated Metal‐Free Hydrosilylation of Alkenes through Selective Hydrogen Atom Transfer for Si−H Activation
Metal-free direct alkylation of unfunctionalized allylic/benzylic sp<sup>3</sup>C–H bonds via photoredox induced radical cation deprotonation