Brian Gold

Escape from Flatland: Pericyclic Reactions and Rearrangements of Diazofluorene with Biarylcyclooctynes for the Generation of Helicene‐Like Phenanthro‐Pyrazoles

Oxa-azabenzobenzocyclooctynes (O-ABCs): heterobiarylcyclooctynes bearing an endocyclic heteroatom

Boronic acid with high oxidative stability and utility in biological contexts

Molecular basis for catabolism of the abundant metabolite trans-4-hydroxy-L-proline by a microbial glycyl radical enzyme

Sub-picomolar Inhibition of HIV-1 Protease with a Boronic Acid

Stereoelectronic Effects on Structure and Reactivity of Organic Molecules: Origins and Consequences

Alkenes as Alkyne Equivalents in Radical Cascades Terminated by Fragmentations: Overcoming Stereoelectronic Restrictions on Ring Expansions for the Preparation of Expanded Polyaromatics

ChemInform Abstract: Design of Leaving Groups in Radical C—C Fragmentations: Through‐Bond 2c—3e Interactions in Self‐Terminating Radical Cascades.

Design of Leaving Groups in Radical CC Fragmentations: Through‐Bond 2c–3e Interactions in Self‐Terminating Radical Cascades

Rerouting Radical Cascades: Intercepting the Homoallyl Ring Expansion in Enyne Cyclizations via C–S Scission

Alkynyl Crown Ethers as a Scaffold for Hyperconjugative Assistance in Noncatalyzed Azide–Alkyne Click Reactions: Ion Sensing through Enhanced Transition-State Stabilization

“Two Functional Groups in One Package”: Using Both Alkyne π-Bonds in Cascade Transformations

Moderating Strain without Sacrificing Reactivity: Design of Fast and Tunable Noncatalyzed Alkyne–Azide Cycloadditions via Stereoelectronically Controlled Transition State Stabilization

Divergent Cyclizations of 1-R-Ethynyl-9,10-anthraquinones: Use of Thiourea as a “S^2–” Equivalent in an “Anchor-Relay” Addition Mediated by Formal C–H Activation

Strain control in nucleophilic cyclizations: reversal of <i>exo</i>‐selectivity in cyclizations of hydrazides of acetylenyl carboxylic acids by annealing to a pyrazole scaffold

Tandem Nucleophilic Addition/Fragmentation of Vinylogous Acyl Nonaflates for the Synthesis of Functionalized Alkynes, with New Mechanistic Insight

ChemInform Abstract: Tandem Nucleophilic Addition/Fragmentation of Vinylogous Acyl Nonaflates for the Synthesis of Functionalized Alkynes, with New Mechanistic Insight.