Area of research
Materials Chemistry · Inorganic Chemistry
Research interest
Research interests include Crystallization and Solubility Studies, X-ray Diffraction in Crystallography, Metal-Catalyzed Oxygenation Mechanisms, and Metal complexes synthesis and properties.
Promiscuity in Molecular Mimics of the Cysteine Dioxygenase: Effects of Selenium in the Substrate and Cobalt as the Central Metal Ion
Controlling the Activation at Ni<sup>II</sup>−CO<sub>2</sub><sup>2−</sup> Moieties through Lewis Acid Interactions in the Second Coordination Sphere
Appropriation of group II metals: synthesis and characterisation of the first alkaline earth metal supported transition metal carbonite complexes
Trispyrazolyl Borate Iron Thiolate Complexes and the Dependence of their O<sub>2</sub>‐Reactivity on the Reaction Space
A Dinuclear Re Complex as a Multi Talent – Photocatalysis and Electrocatalysis combined with Spectroscopy
Synthesis of Intramolecular P/Al‐Based Frustrated Lewis Pairs via Aluminum‐Tin‐Exchange and their Reactivity toward CO<sub>2</sub>
A strained intramolecular P/Al-FLP and its reactivity toward allene
Evidence of Sulfur Non‐Innocence in [Co<sup>II</sup>(dithiacyclam)]<sup>2+</sup>‐Mediated Catalytic Oxygen Reduction Reactions
Reactivity of Xantphos‐Type Rhodium Complexes Towards SF<sub>4</sub>: SF<sub>3</sub> Versus SF<sub>2</sub> Complex Generation
A New Thiolate‐Bound Dimanganese Cluster as a Structural and Functional Model for Class Ib Ribonucleotide Reductases
Indolyl Phosphine Nickel(II) Fluorido Complexes: Synthesis and Intermediates in <i>Suzuki–Miyaura</i> Cross‐Coupling Reactions
Secondary Phosphine Oxide Functionalized Gold Clusters and Their Application in Photoelectrocatalytic Hydrogenation Reactions
Ring-Opening of THF via an Intramolecular P/Al-Based Frustrated Lewis Pair: Assistance by C<sub>6</sub>F<sub>5</sub> Groups beyond Electronegativity?
Transformation of Formazanate at Nickel(II) Centers to Give a Singly Reduced Nickel Complex with Azoiminate Radical Ligands and Its Reactivity toward Dioxygen
A rare isostructural series of 3d–4f cyanido-bridged heterometallic squares obtained by assembling [Fe<sup>III</sup>{HB(pz)<sub>3</sub>}(CN)<sub>3</sub>]<sup>−</sup> and Ln<sup>III</sup> ions: synthesis, X-ray structure and cryomagnetic study
Structural Determination of an Unusual Cu<sup>I</sup>‐Porphyrin‐π‐Bond in a Hetero‐Pacman Cu‐Zn‐Complex
High‐spin square planar iron(II) alkali metal siloxide complexes – influence of the alkali metal and reactivity towards O<sub>2</sub> and NO
Mimicking of the histidine brace structural motif in molecular copper(I) compounds
Stoichiometric Formation of an Oxoiron(IV) Complex by a Soluble Methane Monooxygenase Type Activation of O<sub>2</sub> at an Iron(II)-Cyclam Center
Elucidation of Cooperativity in CO<sub>2</sub> Reduction Using a Xanthene-Bridged Bimetallic Rhenium(I) Complex
Mercaptothiacalixarenes Steer 24 Copper(I) Centers to form a Hollow‐Sphere Structure Featuring Cu<sub>2</sub>S<sub>2</sub> Motifs with Exceptionally Short Cu⋅⋅⋅Cu Distances
Selective Transformation of Nickel‐Bound Formate to CO or C−C Coupling Products Triggered by Deprotonation and Steered by Alkali‐Metal Ions
Electron transfer within β-diketiminato nickel bromide and cobaltocene redox couples activating CO<sub>2</sub>
Routes to Heterotrinuclear Metal Siloxide Complexes for Cooperative Activation of O<sub>2</sub>
Sensitized Photochemical CO<sub>2</sub> Reduction by Hetero‐Pacman Compounds Linking a Re<sup>I</sup> Tricarbonyl with a Porphyrin Unit
The Influence of Alkali Metal Ions on the Stability and Reactivity of Chromium(III) Superoxide Moieties Spanned by Siloxide Ligands
Switching from a Chromium(IV) Peroxide to a Chromium(III) Superoxide upon Coordination of a Donor in the trans Position
Activation of tetrafluoropropenes by rhodium(<scp>i</scp>) germyl and silyl complexes
<i>In situ</i> generation of Ph<sub>3</sub>PO in cyanido-bridged heterometallic {Fe<sup>III</sup>Ln<sup>III</sup>}<sub>2</sub> molecular squares (Ln = Eu, Sm)
A Silylene–Borane Lewis Pair as a Tool for Trapping a Water Molecule: Silanol Formation and Dehydrogenation