Area of research
Materials Chemistry · Inorganic Chemistry
Research interest
Research interests include Metal-Catalyzed Oxygenation Mechanisms, Crystallization and Solubility Studies, X-ray Diffraction in Crystallography, and Metal complexes synthesis and properties.
Debate of Nucleophilic versus Electrophilic Oxidative Aldehyde Deformylation by Mononuclear Nonheme Iron(III)-Peroxo and Iron(IV)-Oxo Complexes
An Oxoiron(IV) Complex Supported by an N‐Alkylated Cyclam Ligand System Containing a Pendant Alcohol Moiety
M(III) Site‐Driven Structural Engineering on Lead‐Free Layered Double Perovskite Nanocrystals with Enhanced Photoelectrochemical Activity
Mechanistic Promiscuity in Cobalt‐Mediated CO <sub>2</sub> Reduction Reaction: One‐ Versus Two‐Electron Reduction Process
Identification, Characterization, and Electronic Structures of Interconvertible Cobalt–Oxygen TAML Intermediates
Long‐Term Stability of Light‐Induced Ti<sup>3+</sup> Defects in TiO<sub>2</sub> Nanotubes for Amplified Photoelectrochemical Water Splitting
Trapping of a phenoxyl radical at a non-haem high-spin iron(II) centre
Origin of Unprecedented Formation and Reactivity of Fe<sup>IV</sup>═O Species via Oxygen Activation: Role of Noncovalent Interactions and Magnetic Coupling
π‐Lewis Base Activation of Carbonyls and Hexafluorobenzene
A bis-Phenolate Carbene-Supported bis-μ-Oxo Iron(IV/IV) Complex with a [Fe<sup>IV</sup>(μ-O)<sub>2</sub>Fe<sup>IV</sup>] Diamond Core Derived from Dioxygen Activation
Unveiling the Spectroscopic Signatures of Poly(3,4-ethylenedioxythiophene) by Controlling Polaron and Bipolaron Concentrations
A Bioinspired Nonheme Fe<sup>III</sup>–(O<sub>2</sub><sup>2–</sup>)–Cu<sup>II</sup> Complex with an <i>S</i><sub>t</sub> = 1 Ground State
Reinvestigation of the mechanism of dioxygen activation at a MnII(cyclam) center
An Iminophosphinite Pincer Iridium Complex: Synthesis and Catalytic Tool for Alkane Transfer Dehydrogenations
Ligand Non-Innocence and Proton Channel Promote Cobalt-Catalyzed Electrochemical CO2 Reduction with Predominant CO Selectivity
Reactivities of iron(IV)-oxido compounds with pentadentate bispidine ligands
Evidence of Sulfur Non‐Innocence in [Co<sup>II</sup>(dithiacyclam)]<sup>2+</sup>‐Mediated Catalytic Oxygen Reduction Reactions
A New Thiolate‐Bound Dimanganese Cluster as a Structural and Functional Model for Class Ib Ribonucleotide Reductases
Spectroscopic Properties of a Biologically Relevant [Fe<sub>2</sub>(μ‐O)<sub>2</sub>] Diamond Core Motif with a Short Iron‐Iron Distance
Transition metal-mediated O–O bond formation and activation in chemistry and biology
A bioinspired oxoiron(<scp>iv</scp>) motif supported on a N<sub>2</sub>S<sub>2</sub> macrocyclic ligand
Spectroscopic Characterization of a Reactive [Cu<sub>2</sub>(μ‐OH)<sub>2</sub>]<sup>2+</sup> Intermediate in Cu/TEMPO Catalyzed Aerobic Alcohol Oxidation Reaction
Formation of cobalt–oxygen intermediates by dioxygen activation at a mononuclear nonheme cobalt(<scp>ii</scp>) center
Ligand‐Constraint‐Induced Peroxide Activation for Electrophilic Reactivity
Stable, but still reactive – investigations on the effects of Lewis acid binding on copper nitrene intermediates
Metal-Ligand Multiple Bonds With Group 9–11 Metals
Iron and manganese oxo complexes, oxo wall and beyond
O2 and H2O2 activations at dinuclear Mn and Fe active sites
Stoichiometric Formation of an Oxoiron(IV) Complex by a Soluble Methane Monooxygenase Type Activation of O<sub>2</sub> at an Iron(II)-Cyclam Center
A Pseudotetrahedral Terminal Oxoiron(IV) Complex: Mechanistic Promiscuity in C−H Bond Oxidation Reactions