Area of research
Inorganic Chemistry · Materials Chemistry
Research interest
Research interests include Chemistry, Reactivity (psychology), Nucleophile, Nitrene, Electrophile, and Copper.
Formation of cobalt–oxygen intermediates by dioxygen activation at a mononuclear nonheme cobalt(<scp>ii</scp>) center
Stable, but still reactive – investigations on the effects of Lewis acid binding on copper nitrene intermediates
Trapping of a Highly Reactive Oxoiron(IV) Complex in the Catalytic Epoxidation of Olefins by Hydrogen Peroxide
Trapping of a Highly Reactive Oxoiron(IV) Complex in the Catalytic Epoxidation of Olefins by Hydrogen Peroxide
Nucleophilic versus Electrophilic Reactivity of Bioinspired Superoxido Nickel(II) Complexes
Sulfur substitution in a Ni(cyclam) derivative results in lower overpotential for CO<sub>2</sub> reduction and enhanced proton reduction
A Highly Reactive Oxoiron(IV) Complex Supported by a Bioinspired N<sub>3</sub>O Macrocyclic Ligand
Oxoiron(IV) Tetramethylcyclam Complexes with Axial Carboxylate Ligands: Effect of Tethering the Carboxylate on Reactivity
Four-electron reduction of dioxygen to water by a trinuclear copper complex
A Highly Reactive Oxoiron(IV) Complex Supported by a Bioinspired N<sub>3</sub>O Macrocyclic Ligand
Characterization and Reactivity Studies of a Terminal Copper–Nitrene Species
A New Domain of Reactivity for High‐Valent Dinuclear [M(μ‐O)<sub>2</sub>M′] Complexes in Oxidation Reactions
Characterization and Reactivity Studies of a Terminal Copper–Nitrene Species
A New Domain of Reactivity for High‐Valent Dinuclear [M(μ‐O)<sub>2</sub>M′] Complexes in Oxidation Reactions
Evidence of two-state reactivity in alkane hydroxylation by Lewis-acid bound copper–nitrene complexes
A High‐Valent Heterobimetallic [Cu<sup>III</sup>(μ‐O)<sub>2</sub>Ni<sup>III</sup>]<sup>2+</sup> Core with Nucleophilic Oxo Groups
Redox Non-Innocence of a <i>N</i>-Heterocyclic Nitrenium Cation Bound to a Nickel–Cyclam Core
Mechanism of phenol oxidation by heterodinuclear Ni Cu bis(μ-oxo) complexes involving nucleophilic oxo groups
A High‐Valent Heterobimetallic [Cu<sup>III</sup>(μ‐O)<sub>2</sub>Ni<sup>III</sup>]<sup>2+</sup> Core with Nucleophilic Oxo Groups
Lewis Acid Trapping of an Elusive Copper–Tosylnitrene Intermediate Using Scandium Triflate