Brian M. Hoffman

Nitric oxide inhibits ten-eleven translocation DNA demethylases to regulate 5mC and 5hmC across the genome

Nitric Oxide restricts iron availability and induces quorum sensing in Streptococcus pyogenes

In vitro maturation of fully active [FeFe]-hydrogenase in a defined system including the iron carrier NfuA

Discovery of a New Class of Aminoacyl Radical Enzymes Expands Nature’s Known Radical Chemistry

The Active-Site [4Fe-4S] Cluster in the Isoprenoid Biosynthesis Enzyme IspH Adopts Unexpected Redox States during Ligand Binding and Catalysis

Nitric oxide inhibits FTO demethylase activity to regulate N6-methyladenosine mRNA methylation

<b>Mechanism of Radical <i>S</i>-Adenosyl-</b><scp>l</scp>-methionine Adenosylation: Radical Intermediates and the Catalytic Competence of the 5′-Deoxyadenosyl Radical

[FeFe]‐Hydrogenase: Defined Lysate‐Free Maturation Reveals a Key Role for Lipoyl‐H‐Protein in DTMA Ligand Biosynthesis

Characterization by ENDOR Spectroscopy of the Iron–Alkyl Bond in a Synthetic Counterpart of Organometallic Intermediates in Radical SAM Enzymes

[FeFe]‐Hydrogenase: Defined Lysate‐Free Maturation Reveals a Key Role for Lipoyl‐H‐Protein in DTMA Ligand Biosynthesis

Feeding after spawning and energy balance at spawning are associated with repeat spawning interval in steelhead trout

An ecophysiological explanation for manganese enrichment in rock varnish

Dietary tetradecylthioacetic acid supplementation during the fall prevents an increase in body lipid levels but does not influence precocious male maturation rate in juvenile spring Chinook salmon

Structural and spectroscopic characterization of an Fe(VI) bis(imido) complex

High-Resolution ENDOR Spectroscopy Combined with Quantum Chemical Calculations Reveals the Structure of Nitrogenase Janus Intermediate E₄(4H)

Manganese co-localizes with calcium and phosphorus in Chlamydomonas acidocalcisomes and is mobilized in manganese-deficient conditions

Beyond fossil fuel–driven nitrogen transformations

Organometallic and radical intermediates reveal mechanism of diphthamide biosynthesis

Across the tree of life, radiation resistance is governed by antioxidant Mn ²⁺ , gauged by paramagnetic resonance

Mechanism of Nitrogenase H₂ Formation by Metal-Hydride Protonation Probed by Mediated Electrocatalysis and H/D Isotope Effects

Monovalent Cation Activation of the Radical SAM Enzyme Pyruvate Formate-Lyase Activating Enzyme

Substrate-Dependent Cleavage Site Selection by Unconventional Radical <i>S</i>-Adenosylmethionine Enzymes in Diphthamide Biosynthesis

Organometallic Complex Formed by an Unconventional Radical <i>S</i>-Adenosylmethionine Enzyme

Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

A Closer Look at the Spectroscopic Properties of Possible Reaction Intermediates in Wild-Type and Mutant (<i>E</i>)-4-Hydroxy-3-methylbut-2-enyl Diphosphate Reductase

Biophysical Studies of Metalloenzymes

Biophysical Studies of Metalloenzymes

Biophysical Studies of Metalloenzymes

Biophysical Studies of Metalloenzymes

Biophysical Studies of Metalloenzymes

Star Porphyrazines

Biophysical Studies of Metalloenzymes

Star Porphyrazines

Biophysical Studies of Metalloenzymes

Star Porphyrazines, Solitaire Phthalocyanines and Related Multimetallic Macrocycles

Biophysical Studies of Metalloenzymes

New Conductive and Magnetic Materials

Star Porphyrazines, Solitaire Phthalocyanines and Related Multimetallic Macrocycles

Biophysical Studies of Metalloenzymes

New Conductive and Magnetic Materials

Star Phorphyrazines: Metallomacrocycles and Novel Complexation

Biophysical Studies of Metalloenzymes

New Highly Conducting Molecular Crystals

Biophysical Studies of Metalloproteins

New Highly Conducting Molecular Crystals (Materials Research)

Metalloporphyrins and Metal-Substituted Oxygen-Binding Hemoproteins

New Highly Conducting Molecular Crystals (Materials Research)

Acquisition of Epr/Endor Spectrometer System

Metalloporphyrins and Metal-Substituted Oxygen-Binding Hemoproteins

New Highly Conductive Molecular Crystals